SYNTHESIS AND CHARACTERIZATION OF SOME METAL IONS WITH {[5-(4-CHLOROPHENYL)-1,3,4-OXADIAZOL-2-YL]THIO} ACETIC ACID

Authors

  • Emad Yousif Department of Chemistry, College of Science, Al-Nahrain University, Baghdad-Iraq.
  • Eva Rentschler Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany

Keywords:

carboxylate, 1,3,4-oxadiazole, metal complexes, spectroscopy

Abstract

New metal complexes of the ligand {[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]thio}acetic acid with the metal ions Ni(II), Cu(II), Zn(II), Cd(II) and Sn(II) were prepared in alcoholic medium. The prepared complexes were characterized by FTIR Spectroscopy, electronic spectroscopy 1HNMR, 13CNMR, magnetic susceptibility and conductivity measurements. From the spectral measurements, monomer structures for the complexes were proposed. Square planar geometry was proposed for the copper complex. The other complexes were proposed to be tetrahedral.

 

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Published

2010-06-01

Issue

Vol. 13 No. 2 (2010): June

Section

Articles

How to Cite

(1)
SYNTHESIS AND CHARACTERIZATION OF SOME METAL IONS WITH {[5-(4-CHLOROPHENYL)-1,3,4-OXADIAZOL-2-YL]THIO} ACETIC ACID. ANJS 2010, 13 (2), 86-92.

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